Iodometry is an indirect titration method whereas iodimetry is a direct titration method. This is the main difference between Iodometry and. Iodometry and iodimetry are two common titration methods useful in analytical chemistry. Iodometry is the quantitative analysis of a solution of. IODIMETRIC TITRATIONS When an analyte that is a reducing agent (like hypo) is titrated directly with a standard iodine solution, the method is called “iodimetry”.

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Types of Chemical Reactions. Note that iodometry involves indirect titration of iodine liberated iodimetricc reaction with the analyte, whereas iodimetry involves direct titration using iodine as the titrant.

Difference Between Iodometry and Iodimetry

For analysis of antimony V compounds, some tartaric acid is added to solubilize the antimony III product. For prolonged titrations, it is advised to add dry ice to the titration mixture to displace air from the erlenmeyer flask so titratiion to prevent the aerial oxidation of iodide to iodine.

You also know that an analyte is the substance being analyzed. Iodine forms a deep-blue colour complex with starch and as the Iodine breaks down to Iodide ions, the colour disappears. Istituto Magistrale “Leonardo da Vinci” di Alba.

Difference Between Iodometry and Iodimetry l Iodometry vs Iodimetry

Introduction to iodometric and iodimetric iodojetric An oxidaizing agent is the element or compound in a redox reaction that oxidaizes another species. National Environmental Methods Index.


Until now, most of the titrations that we have performed in the laboratory are direct titrations. And a standard solution of this is used for the iodometric titrations. In fact, both these terms refer to different methods of using Iodine in titrations to determine the concentration of an analyte under investigation. The reaction between the analyte and the titrant generates a product. We divide these titrations into two types. Under strongly acidic solution, the above equilibrium lies far to the right hand side, but is reversed in almost neutral solution.

Iodometric titration of copper Sample: Introduction to iodometric and iodimetric titrations Third: Introduction to iodometric and iodimetric titrations Examples Acid-base Quantification of acetic acid in vinegar Complexometric Quantification of chloride Cl- in water Precipitation Water Hardness Calcium and magnesium Redox Quantification of hydrogen peroxide H2O2 Slide 4: Wikipedia ; burette, source: Examples of reducing agents: Iodometry is commonly employed to determine the active amount of hypochlorite in bleach responsible for the bleaching action.

With iodine and starch in the mixture, it will appear in dark-blue colour, but at the end point when all the iodine is finished, the dark colour will disappear. The tasks that you will do involve completing the same flow-charts which I will use in the talk. As you know, a direct titration involves one reaction between the analyte and the titrant.


There are a lot of redox titrations iodimetrix the most common ones are: In IodometryIodine gets oxidized first and then reduced by a reducing agent. Colour of the starch solution in the presence of I2. Oxidation reduction titration The addition of an excess of I 2 makes the solution turn dark blue indicating that all the sulphur dioxide in the sample has been titrated.

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Do you remember in which titrations the titrant is in the Erlenmeyer flask? Consequently, in the first reaction The analyte reacts with an excess of iodur to generate iode.

Le lezioni del Corso 1. Here are the same examples, this time.

Iodine dissolves in the iodide-containing solution to give triiodide ions, which have a dark brown color. The total sulphur dioxide in the wine sample is determined through direct iodimetric titration using starch as the indicator.

Some typical kinds of chemical reactions: The basis of titration is a reaction between the analyte and a standard reagent known as the titrant. Thi is another of the advantages of using sulphur dioxide because it guarantees the stability of the product over time. The standard solution is sodium thiosulfate. Sodium thisoufate Slide 8: The analytical chemistry laboratory. Exactly, the other classical quantitative chemical analysis is gravimetry.

Safety in the laboratory.